The game files store 101 as a sentinel for moves that cannot miss, so this move never misses.
Learn list
Pokemon that learn Safeguard
Alakazam
Psychic · 500
Mega Alakazam
Psychic · 600
Alcremie (Caramel Swirl)
Fairy · 495
Alcremie (Lemon Cream)
Fairy · 495
Alcremie (Matcha Cream)
Fairy · 495
Alcremie (Mint Cream)
Fairy · 495
Alcremie (Rainbow Swirl)
Fairy · 495
Alcremie (Ruby Cream)
Fairy · 495
Alcremie (Ruby Swirl)
Fairy · 495
Alcremie (Salted Cream)
Fairy · 495
Alcremie (Vanilla Cream)
Fairy · 495
Altaria
Dragon / Flying · 490
Mega Altaria
Dragon / Fairy · 590
Ampharos
Electric · 510
Mega Ampharos
Electric / Dragon · 610
Audino
Normal · 445
Mega Audino
Normal / Fairy · 545
Aurorus
Rock / Ice · 521
Barbaracle
Rock / Water · 500
Mega Barbaracle
Rock / Fighting · 600
Chandelure
Ghost / Fire · 520
Mega Chandelure
Ghost / Fire · 620
Chimecho
Psychic · 455
Mega Chimecho
Psychic / Steel · 555
Clefable
Fairy · 483
Mega Clefable
Fairy / Flying · 583
Cofagrigus
Ghost · 483
Delphox
Fire / Psychic · 534
Mega Delphox
Fire / Psychic · 634
Dragonite
Dragon / Flying · 600
Mega Dragonite
Dragon / Flying · 700
Drampa
Normal / Dragon · 485
Mega Drampa
Normal / Dragon · 585
Espeon
Psychic · 525
Floette (Eternal Flower)
Fairy · 551
Mega Floette
Fairy · 651
Florges (Blue Flower)
Fairy · 552
Florges (Orange Flower)
Fairy · 552
Florges (Red Flower)
Fairy · 552
Florges (White Flower)
Fairy · 552
Florges (Yellow Flower)
Fairy · 552
Froslass
Ice / Ghost · 480
Mega Froslass
Ice / Ghost · 580
Gallade
Psychic / Fighting · 518
Mega Gallade
Psychic / Fighting · 618
Gardevoir
Psychic / Fairy · 518
Mega Gardevoir
Psychic / Fairy · 618
Gourgeist (Jumbo Variety)
Ghost / Grass · 494
Gourgeist (Large Variety)
Ghost / Grass · 494
Gourgeist (Medium Variety)
Ghost / Grass · 494
Gourgeist (Small Variety)
Ghost / Grass · 494
Hatterene
Psychic / Fairy · 510
Kangaskhan
Normal · 490
Mega Kangaskhan
Normal · 590
Klefki
Steel / Fairy · 470
Meganium
Grass · 525
Mega Meganium
Grass / Fairy · 625
Meowstic (Female)
Psychic · 466
Meowstic (Male)
Psychic · 466
Mega Meowstic (Male)
Psychic · 566
Mega Meowstic (Female)
Psychic · 566
Milotic
Water · 540
Mimikyu (Busted Form)
Ghost / Fairy · 476
Mimikyu (Disguised Form)
Ghost / Fairy · 476
Mr. Rime
Ice / Psychic · 520
Musharna
Psychic · 487
Ninetales
Fire · 505
Alolan Ninetales
Ice / Fairy · 505
Oranguru
Normal / Psychic · 490
Reuniclus
Psychic · 490
Runerigus
Ground / Ghost · 483
Sableye
Dark / Ghost · 380
Mega Sableye
Dark / Ghost · 480
Slowbro
Water / Psychic · 490
Galarian Slowbro
Poison / Psychic · 490
Mega Slowbro
Water / Psychic · 590
Slowking
Water / Psychic · 490
Galarian Slowking
Poison / Psychic · 490
Slurpuff
Fairy · 480
Starmie
Water / Psychic · 520
Mega Starmie
Water / Psychic · 620
Sylveon
Fairy · 525
Trevenant
Ghost / Grass · 474
Vivillon (Archipelago Pattern)
Bug / Flying · 411
Vivillon (Continental Pattern)
Bug / Flying · 411
Vivillon (Elegant Pattern)
Bug / Flying · 411
Vivillon (Fancy Pattern)
Bug / Flying · 411
Vivillon (Garden Pattern)
Bug / Flying · 411
Vivillon (High Plains Pattern)
Bug / Flying · 411
Vivillon (Icy Snow Pattern)
Bug / Flying · 411
Vivillon (Jungle Pattern)
Bug / Flying · 411
Vivillon (Marine Pattern)
Bug / Flying · 411
Vivillon (Meadow Pattern)
Bug / Flying · 411
Vivillon (Modern Pattern)
Bug / Flying · 411
Vivillon (Monsoon Pattern)
Bug / Flying · 411
Vivillon (Ocean Pattern)
Bug / Flying · 411
Vivillon (Poké Ball Pattern)
Bug / Flying · 411
Vivillon (Polar Pattern)
Bug / Flying · 411
Vivillon (River Pattern)
Bug / Flying · 411
Vivillon (Sandstorm Pattern)
Bug / Flying · 411
Vivillon (Savanna Pattern)
Bug / Flying · 411
Vivillon (Sun Pattern)
Bug / Flying · 411
Vivillon (Tundra Pattern)
Bug / Flying · 411
Volcarona
Bug / Fire · 550
Whimsicott
Grass / Fairy · 480
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